应变纤锌矿ZnO/MgxZn1-xO量子点中离子施主束缚激子的光学性质

Within the framework of the effective-mass approximation and the dipole approximation, considering the three-dimensional confinement of the electron and hole and the strong built-in electric field(BEF) in strained wurtzite Zn O/Mg0:25Zn0:75O quantum dots(QDs), the optical properties of ionized donor-bound excitons(D+, X)are investigated theoretically using a variational method. The computations are performed in the case of finite band offset. Numerical results indicate that the optical properties of(D+, X) complexes sensitively depend on the donor position, the QD size and the BEF. The binding energy of(D+, X) complexes is larger when the donor is located in the vicinity of the left interface of the QDs, and it decreases with increasing QD size. The oscillator strength reduces with an increase in the dot height and increases with an increase in the dot radius. Furthermore, when the QD size decreases, the absorption peak intensity shows a marked increment, and the absorption coefficient peak has a blueshift. The strong BEF causes a redshift of the absorption coefficient peak and causes the absorption peak intensity to decrease remarkably. The physical reasons for these relationships have been analyzed in depth.     

粉煤气化装置管道应力分析

利用CAESARⅡ软件建立了某粉煤气化装置一级炉至二级炉设备及管道的整体模型,分析了管道应力及设备管口受力状况,并依此利用ANSYS软件对二级炉设备管口应力进行了详细分析.分析表明,管道支吊架调整后,管道及设备应力及应变符合规范要求.     

Highly active sites of low spin FeⅡN4species:The identification and the ORR performance

Over recent years,catalytic materials of Fe-N-C species have been recognized being active for oxygen reduction reaction(ORR).However,the identification of active site remains challenging as it generally involves a pyrolysis process and mixed components being obtained.Herein Fe₃C/C and Fe₂N/C samples were synthesized by temperature programmed reduction of Fe precursors in 15%CH₄/H₂and pure NH₃,respectively.By acid leaching of Fe₂N/C sample,only single sites of FeN₄species were presented,providing an ideal model for identification of catalytic functions of the single sites of FeN₄in ORR.A correlation was conducted between the concentration of Fe^ⅡN₄in low spin state by Mossbauer spectra and the kinetic current density at 0.8 V in alkaline media,and such a structure-performance correlation assures the catalytic roles of low spin Fe^ⅡN₄ species as highly active sites for the ORR.     

锚杆锯切设备自动化改造技术应用

通过对锚杆锯切设备的设计、改进情况进行总结，详细介绍了自动化改造前后的设备工作原理、结构组成以及各部分工作过程动作描述等内容，根据改造前后的各项数据统计分析，列出了自动化改造后产品质量、生产效率和企业的利润的变化，同时还有设备故障率、工人劳动强度、设备操作人员数量的减少以及工厂生产环境由污染型转变成节能环保型企业等相关内容，展示所取得的有益效果。     

“都林”机器人内板连续式喷涂技术应用浅析

结合新工厂的应用经验,通过对"都林"机器人的喷涂方式、布局、雾化器配置选型、参数设置、仿形设计及品质控制要点等方面的分析,总结了连续式喷涂的优势及技术控制要求。     

再生骨料自密实清水混凝土配合比优化及表观性能试验研究

利用再生粗骨料制备再生骨料自密实清水混凝土,采用正交试验的方法对再生骨料自密实清水混凝土的配合比进行优化,探究了水胶比、砂率及胶凝材料含量对混凝土工作性能、力学性能以及表观性能的影响规律及显著性.通过对试验结果的极差分析,发现胶凝材料含量对混凝土坍落扩展度影响最大,其次是砂率,水胶比的影响最小;对于7d抗压强度的影响程度从大到小依次为水胶比、砂率、胶凝材料含量;混凝土表面灰度标准差受胶凝材料含量影响最大,其次是水胶比和砂率;对混凝土表面气孔率的影响程度从大到小依次为胶凝材料含量、砂率、水胶比.通过方差分析得到水胶比与砂率对再生骨料自密实清水混凝土的7d抗压强度具有显著性影响;胶凝材料含量对坍落扩展度、灰度标准差和气孔率有显著性影响.